Print ISSN: 1681-6900

Online ISSN: 2412-0758

Author : Abdul Hussin Zaidan, Basima

Synthesis and study of the Novel tetradented ligand type N2O2 and its complexes with (Mn(II),Co (II),Ni (II) and Cu(II)) ions

Ahmad Thabet Numan; Maysoon T.Tawfiq; Basima Abdul Hussin Zaidan

Engineering and Technology Journal, 2009, Volume 27, Issue 9, Pages 1880-1890

A new Schiff base ligand Bis-1,4-di[N-3-(2-hydroxy-1-amino)- acetophenonylidene] benzylidene [L] and its complexes with (Mn(II),Co(II),Ni(II and Cu(II)) were synthesized . The ligand was prepared in two steps. In the first step a solution of (terphthalaldehyde) in methanol reacts under reflux with (p-aminoacetophenone) to give an intermediate compound [1-[3-({4-[(3-Acetyl-phenylimino)-methyl]-benzylidene}-amino)-phenyl]- ethanone which reacts in the second step with (2-Amino-phenol) giving the mentioned
ligand. The complexes were synthesized by addition the corresponding metal salt solution to the solution of the ligand in methanol under reflux in (1:1) metal to ligand ratio. On the basis of, molar conductance, I.R., UV-Vis, HPLC, chloride content and
atomic absorption, the complexes may be formulated as K2[M(L)Cl2 ] were MII = Mn ,Co, Ni and Cu metal ions. The data of these measurements suggest an octahedral geometry for Mn(II),Co(II) and Cu(II) complexes and a square planar for Ni(II) complex