Print ISSN: 1681-6900

Online ISSN: 2412-0758

Keywords : complexes of metal ions

Preparation, Characterization and Structural Studies of Some Phenyl Isothiocynate Metal Complexes

Asmaa K. Ayal; Shatha F. Nareen; Abbas Ali Salih Al-Hamdani

Engineering and Technology Journal, 2011, Volume 29, Issue 2, Pages 253-260

Phenyl isothiocynate complexes of Cu (I), Cu(II), Mn(II), Fe(II), Fe (III),
Cr(III) and Ce(III) have been prepared and analyzed spectroscopicaly by Elemental
analyses and atomic absorption technique; the magnetic susceptibility and the
conductivity have also been measured and molar ratio of Ligand: Matale with mole
ratio method and Job Method. From these measurement it is concluded that Cu(I),
Fe(III) and Mn(II) form tetrahedral complexes, while Cu (II) Forms square planner
complexes, and Cr (III) and Ce(III) forms octahedral complexes.