Keywords : Spectroscopic Studies
Synthesis, Structural and Spectroscopic Study of Complexes of Tetradentate Schiff Base Derived from MalonylDihydrazide with Cr(III), Mn(II), Co(II), Cu(II) and Zn(II) Ions
Engineering and Technology Journal,
2017, Volume 35, Issue 1, Pages 50-56
This paper describes the synthesis of a new derivative dihydro-3H-indol-3-ylidene propane dihydrazide [L], which have been obtained from the reaction between malonyl di-hydrazide and an ethanollic solution of isatin. Tetradentatemacrocyclic ligand [L] was characterized by (C.H.N), (FT-IR), (UV-Vis), and 1H.NMR.A series of the used metal complexes have been synthesized by the prepared ligand [L] reaction with some transition metal ions. The isolated complexes were Cr(III), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) also characterized using different techniques such as (FT-IR), and (UV-Vis) spectroscopies, (C.H.N), flam atomic absorption in addition to the magnetic susceptibility and molar conductivity measurement. Al complexes were octahedral in geometry except for Zn (II) complex, which was tetrahedral.