University of Technology-IraqEngineering and Technology Journal1681-690040320220301Best Conditions for Extraction and Stripping of Iron from Chloridic Aqueous Medium43344017337910.30684/etj.v40i3.2101ENMazin A.BedenMarine Science Center, University of Basrah, Basrah, Iraq.Wadood T.MohammedChemical Engineering Dept., College of Engineering, University of Baghdad, Baghdad, Iraq.Salah A.NemaChemical Engineering Dept., College of Engineering, University of Basrah, Basrah, Iraq.Journal Article20210401Pure iron is used as an additive for food and drugs to provide the human body with an important element which is iron. For this purpose, iron should be pure and in powder form, the extraction process can supply this type of iron. In this study, extraction of iron from an aqueous solution was done by cyclohexanone as an extractant. The parameters of extraction and stripping processes were studied and assessed the best values which give a high yield of separated iron from ore or any source of iron. For the preliminary study, three general parameters were studied and the best values are agitation time (10 min.), agitation speed (400 rpm), and temperature (30C). In the main study for the extraction process, there are four parameters were investigated and the optimum values are phase ratio (O/A) (1/1), iron concentration (conversely relationship), extractant concentration (proportional relationship), and normality (5 N). The best values for stripping process parameters are phase ratio(A/O) (1/2 – 1/1) and normality of strip solution (0.1 N). The extraction technique is very important in Pharmaceutical industries to produce different suitable metals associated with food and drugs. The extraction technique was detected as an appropriate method to separate iron and introduce it in pure powder form.https://etj.uotechnology.edu.iq/article_173379_fe4c3f58f3592a1b9ddc033935c68405.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301A Review of the Natural Gas Purification from Acid Gases by Membrane44145017338010.30684/etj.v40i3.1983ENDheyaa JasimAl-Amarah University College, Department of Petroleum Engineering, Maysan, IraqThamer J.MohammedChemical Engineering Dept.,University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Mohammad F.AbidChemical Engineering Dept.,University of Technology-Iraq, Alsina‟a Street, 10066 Baghdad, Iraq.Journal Article20210120This study aims to shed light on natural gas as an important and promising energy source. This energy source is the fastest-growing source in the world due to the increasing global demand. In this paper, the rates of growth in global demand for natural gas according to the latest reports since 1984, as well as the gas specifications required for transport and storage, acid gases, including absorption, desorption, Cryogenic and separation by membranes, are discussed with the advantages and disadvantages of each method. Focusing are presented. In addition to the primary treatment processes that take place on the gas, the most important of which is the removal of acid gases. Processes for removing on the membrane separation process as the most promising process in this field and reviewing all the research that is discussed in details of this process.https://etj.uotechnology.edu.iq/article_173380_61664aed150c1cf05d7f1b17aa70cd55.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301Investigation of Carboxymethyl Cellulose and Barite Additives on the Corrosion Characteristics of Water-Based Drilling Mud45145817346810.30684/etj.v40i3.1555ENRana A.AzeezOil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, IraqNajem AlrubaieyOil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Mohamed GaziOil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Journal Article20200107Drilling fluids can be considered complex liquids containing several desired materials. These materials (small additives) are specialty products that serve a specific need, such as controlling the rheological properties of the drilling fluid and reducing corrosion for operational drilling of both oil and gas wells. Additives used to resist corrosion are called corrosion inhibitors. Previous research has shown that polymers such as Carboxymethyl Cellulose (CMC) have high characteristics of corrosion inhabitation in an aggressive environment. In this study, the effect of adding two samples of additives, CMC and Barite, on the corrosion of carbon steel in Iraqi bentonite water base mud solution has been evaluated using the weight loss technique. The study focuses on determining and comparing the corrosion characteristics of these mud additives. All the experiments were carried out in static flow and at room temperature. Results show that CMC works as a good inhibitor when added to bentonite/barite mud. The calculated corrosion rates of 0.95mpy, 0.75mpy, 0.53mpy, 0.49mpy were found for bentonite mud, bentonite/barite mud, bentonite/CMC mud, and bentonite/CMC/barite mud, respectively. This would result in an inhibitor efficiency of about 50%.https://etj.uotechnology.edu.iq/article_173468_1e4d91a0bc8bdd8630a32fa7a493cd7d.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301Hydrochemical and Environmental Assessment of Groundwater in Al-Yusufiyah District South-west Baghdad, Iraq45947117347710.30684/etj.v40i3.2045ENRafal AbdulrazzaqCivil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Tariq AbedHussainCivil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Ghufran F.JumaahCivil Engineering Dept, University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Journal Article20210309Groundwater in Yusufiyah represents the main water source for drinking and irrigation purposes in the dry season, so this research was conducted to assess and evaluate the hydrochemistry of groundwater in this area. (15) wells were selected for sampling in this area with depth ranges between 10-20 meters. , Groundwater generally flows from east to west and from northeast to southwest.Physical parameters for water samples were measured included temperature, pH, electrical conductivity (EC), and total dissolved solids (TDS),where the chemical parameters included major cations (Ca+2, Mg+2, Na+2, and K+) and major anions (NO<sub>3</sub><sup>-1</sup>, SO<sub>4</sub><sup>-2</sup>,Cl<sup>-</sup>, and HCO<sub>3</sub><sup>-</sup>). The results indicated that groundwater in the study area isnot suitable for human drinking due to high concentrations in(CL=435 ppm), (SO4<sup>-2 </sup>=769 ppm), (HCO<sup>-3</sup>=280 ppm),(TDS=2375 ppm), and (EC=2899µc). These values exceeded the standard limits of WHO. On the other hand, results show that this water was suitable for irrigation (good and Permissible except for well no.1,8,12,13, which wasnot suitable for all irrigation crops due to an increase in (SAR, Na) to the Don classification 1995.https://etj.uotechnology.edu.iq/article_173477_18c2cf0210cb9d4fa4a0f5e467f6b848.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301Curcumin Loaded onto Magnetic Mesoporous Material MCM-41 for Controlled and Released in Drug Delivery System47248317348110.30684/etj.v40i3.2174ENNidhal A.AtiyahChemical Engineering Dept, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.Mohammed A.AtiyaChemical Engineering, Al-Khawarizmi College of Engineering, University of Baghdad.Talib M.AlbayatiChemical Engineering Dept, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.0000-0001-5619-7760Journal Article20210520In this work, the mesoporous silica nanoparticles (MSNs) of type MCM-41 were manufactured and modified with Fe<sub>3</sub>O<sub>4</sub> to load curcumin (CUR) CUR@Fe<sub>3</sub>O<sub>4</sub>/MCM-41 as an efficient carrier in drug delivery systems. X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FT-IR), and nitrogen adsorption-desorption isotherms were used to characterize the three samples: pure MCM-41, Fe<sub>3</sub>O<sub>4</sub>/MCM-41, & CUR@Fe<sub>3</sub>O<sub>4</sub>/MCM-41. Adsorption processes tests were carried out to determine the impact of various variables on the CUR load efficiency. These variables were the carrier dosage, pH, contact time, and initial CUR concentration. The maximal drug loading efficiencies (DL %) were 15.78 % and 22.98 %, respectively. According to the data, The Freundlich isotherm had a stronger correlation coefficient R<sup>2</sup>= 0.999 for MCM-41, while the Langmuir isotherm had a greater R<sup>2</sup> of 0.9666 for Fe<sub>3</sub>O<sub>4</sub>/MCM-41. A pseudo-second-order kinetic model fits well with R<sup>2</sup>=0.9827 for MCM-41 and 0.9994 for Fe<sub>3</sub>O<sub>4</sub>/MCM-41. Phosphate Buffer Solution (PBS) with a pH of 7.4 was utilized to study CUR release behavior. According to the research, the maximum release for MCM-41 and Fe<sub>3</sub>O<sub>4</sub>/MCM-41 might be 74.1 % and 25.19 % after 72 h, respectively. Various kinetic release models were used, including First-order, Korsmeyer-Peppas, Hixson and Crowell, Higuchi, and Weibull. After 72h, the drug release data were fit using a Weibull kinetic model with an R<sup>2</sup> of 0.944 and 0.764 for MCM-41 and Fe<sub>3</sub>O<sub>4</sub>/MCM-41, respectively.https://etj.uotechnology.edu.iq/article_173481_fc7310b390635480197a7cca453cc026.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301Air-lift Reactor's Characterization via Computational Fluid Dynamic (CFD): Review48449717349110.30684/etj.v40i3.2261ENMarwa M.JasimChemical Engineering Dept., University of Technology-Iraq, Alsina’a Street,10066 Baghdad, Iraq.Thamer J.MohammedChemical Engineering Dept., University of Technology-Iraq, Alsina’a Street,10066 Baghdad, Iraq.Laith S.SabriChemical Engineering Dept., University of Technology-Iraq, Alsina’a Street,10066 Baghdad, Iraq.Journal Article20210626Airlift reactors are seen as the most promising reactor for many valuable productions such as algae culturing. However, this kind of reactor still needs more information and data to understand its phenomena due to limited studies. Also, to reduce the time and offers obtained with sufficient reactor design, capable of achieving high productivities, Computational Fluid Dynamics (CFD) could play an important role in optimizing the reactor design by analyzing the interaction of hydro-dynamics. This review presents the literature review on the recent CFD work for such a reactor that addressed the fluid dynamics parameters, such as bubble dynamics. Earlier researches find more reports utilizing uniform bubble diameter in CFD simulations. However, the latest research in the CFD modeling of multi-phase flow reactors showed that the description of the bubble has significant effects on the performance of the simulation. As a result, systematic research into the impact of bubble diameter on the simulation results of the CFD was performed. Finally, we present and discuss the CFD modeling approaches, a Governing equation such as Eulerian-Eulerian (E-E), and closure such as the drag force.https://etj.uotechnology.edu.iq/article_173491_f76dd74d3c4563ed9a8f1395db94f319.pdfUniversity of Technology-IraqEngineering and Technology Journal1681-690040320220301The Use of Inexpensive Sorbents to Remove Dyes from Wastewater - A Review49851517362710.30684/etj.v40i3.2281ENFiras Sh.Ahmedchemical engineering department , university of technology , Baghdad, IraqAdnan A.Abdul RazakChemical Engineering Dept., University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.May A.MuslimChemical Engineering Dept., University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.Journal Article20210714Dyes are utilized in various industrial applications, and some businesses' effluents include hazardous dyes. Humans, aquatic creatures, and the environment are all harmed by dyes. As a result, adequately treated dyes that manage wastewater must be before being discharged into nearby bodies of water. Adsorption has proven to be high and cost-effective in removing dyes from wastewater. The sorbent material for dye removal from industrial effluent is activated carbon, but its high cost limits massive-scale utilization. The use of cost-effective adsorbents for wastewater discharge dye elimination is discussed and analyzed in this paper. This review underlines and displays a preview of these IASs, including natural, industrial, and made-up materiality/wastes and their utilization in removing dyes. Experiments have shown that various inexpensive non-traditional adsorbents lead to effective dye removal. Accordingly, studies dealing with the search for effective and affordable sources from current resources are becoming increasingly crucial for eliminating dye. The excess desire for functional and affordable processing modes and adsorption significance has led to inexpensive alternative sorbents (IASs). The isotherm analysis and adsorption kinetics indicate that Langmuir / Freundlich, besides the pseudo-second-order model, is the most used pattern for convenient empirical adsorption datum. Low-cost by-products from the agricultural, residential, and industrial sectors have been identified as viable wastewater treatment alternatives. They make it possible to remove contaminants from wastewater while also contributing to waste minimization, recovery, and reuse. This review revealed that some IASs, have ratable adsorption capabilities and rapid kinetics, besides having vastly available.https://etj.uotechnology.edu.iq/article_173627_b38cdb05a1f9d908d76db38119b64468.pdf