In this research was the study of the impact of silver nanoparticles solution on the structure and properties of the morphological membrane fibrous hollow PVDF through a dip PVDF Hollow fiber membrane in silver nanoparticle solution preparation via using laser ablation method. The characteristics of membrane and silver Nano particle solution and was examined using X-ray diffraction (XRD)and Scanning Electron Microscopy (SEM) also using laser particle size analyzer for Silver nanoparticles (AgNPs ) to measurement particle size to AgNPs.