Document Type : Research Paper

Authors

1 Chemical Engineering, Department, University of Technology - Iraq

2 Environmental Research Center, University of Technology - Iraq

3 Petroleum Research and Development Center, Ministry of Oil - Iraq

Abstract

The Southern Oil Company, which is operated in North Rumaila oilfield in Basrah/ Iraq, is one of the important companies which produced huge amounts of produced oilfield water. The aim of this study is to treat the produced water by hybrid methods: the process of coagulation-flocculation and microfiltration technique (ceramic membrane) to remove the oil content and improve the water quality to meet the allowable limit of reinjection into the reservoir. Poly-aluminum chloride (PAC), and Ferric Chloride (FeCl3.6H2O) coagulants were used separately and in combination with cationic polyelectrolyte (PE). After produced water was treated with different doses of coagulant, it was passed through the Microfiltration technique/ ceramic membrane (0.5µm) to reach the allowable limit for reinjection. It was found that the best value of oil content after passing through ceramic membrane is 0.2 mg/L at FeCl3.6H2O dose (10 mg/L) combined with PE dose (0.6 mg/L), which was less than the allowable limit for re-injection, (5) ppm.

Keywords

[1] E.L. Hagström, C. Lyles, and M. Pattanayek,
“Produced Water – Emerging Challenges, Risks and
Opportunities,” Environmental Claims Journal, Vol.
28, No. 2, pp. 122-39, 2016.
[2] J. Enid, G. Sullivan, C. Anne, F. Jakle and D.
Martin, “Reuse of oil and gas produced water in southeastern New Mexico: resource assessment, treatment
processes, and policy,” Water International, Vol.40,
No. 5-6, pp. 809-823, 2015.
DOI:10.1080/02508060.2015.1096126
[3] P. Ekins, R. Vanner, and J. Firebrace, “Zero
emissions of oil in water from offshore oil and gas
installations: economic and environmental
implications,” J. Clean. Prod., Vol. 15, pp. 1302–
1315, 2007.
[4] C.E. Clark, J.A. Veil, “Produced water volumes
and management practices in the United States,”
Argonne National Laboratory (ANL), 2009.
[5] U.W.R. Siagian, S. Widodo, A.K. Wardani, and
I.G. Wenten, “Oilfield Produced Water Reuse and
Reinjection with Membrane,” MATEC Web of
Conferences 156, 08005, 2018.
https://doi.org/10.1051/matecconf/201815608005
[6] S. Nesic, and V.V. Streletskaya, “An integrated
approach for produced water treatment and injection,”
Georesursy = Georesources, Vol. 20, No. 1, pp. 25-
31, 2018. DOI: https://doi.org/10.18599/
grs.2018.1.25-31
[7] J. Veil, M. Puder et al., “A white paper
Describing Produced Water From Production of Crude
Oil, Natural Gas, and Coal Bed Methane,” prepared
by Argonne National Laboratory, 2004.
[8] B. Shattuck, “Permian water management
economics: What’s on the margin? Water Management
for the Permian Basin,” Houston, TX, 2015.
[9] H. Yusran, and B. yono, "Pollution Impact and
Alternative Treatment for Produced Water,” E3S Web
of Conferences (ICENIS 2017) 31, 03004, 2018,
https://doi.org/10.1051/e3sconf/20183103004
[10] F. Al-Razi, A. Pendashteh, L.C. Abdullah, D.R.A.
Biak, S.S. Madaeni, and Z.Z. Abidin, “Review of
technologies for oil and gas produced water
treatment,” J. Hazard Matter, Vol. 170, No. (2-3), pp.
530-511, 2009. doi: 10.1016/j.jhazmat.2009.05.044.
[11] L. Cheng, X. Bi, Y. Ni, "Oilfield Produced Water
Treatment by Ozone-Enhanced Flocculation,"
International Conference on Computer Distributed
Control and Intelligent Environmental Monitoring
(CDCIEM), pp.1589-1593, 2011.
[12] T.J. Mohammed, E. Shakir, “Effect of settling
time, velocity gradient, and camp number on turbidity
removal for oilfield produced water,” Egypt. J. Petrol.,
2017. http://dx.doi.org/10.1016/j.ejpe.2016.12.006
[13] Z. Xia, F. Huixia, L. Heming, “Study on the
synthesis and flocculating of a new flocculent,”
international conference on advanced in energy
engineering, 2010.
[14] A.K. Radwan, G. Rashed, “The effect of pH
control on turbidity and NOM removal in conventional
water treatment,” Fifteenth International Water
Technology Conference, IWTC Egypt, 2010.
[15] AWWA, Water Quality and Treatment: A
Handbook of Community Water Supplies, 5th edn.
Raymond Letterman (Technical Editor), McGraw-Hill,
Inc. Washington, D.C. 1999.
[16] E. Shakir, “Reuse of Oilfields Produced Water
Treated by Combined Coagulation-Flocculation and
Microfiltration Technique,” M.Sc. Thesis, Chemical
Engineering/ University of Technology/ 2013.
[17] X. Zheng, “An Integrated Water Injection
Solution for Southern Oilfield of Iraq,” 1st Iraq Oil and
Gas conference (1st IOGC); pp. E149-E152, 2012.