Document Type : Research Paper

Authors

1 Environmental Engineering Dpt. College of Engineering, Mustansiriyah University - Iraq

2 Water Resource Engineering Dpt. College of Engineering, AlMustansiriyah University - Iraq

Abstract

The objective of the study was to prepare activated carbon from date seeds (ADS) and use it as a medium for textile dye adsorption. Batch adsorption of reactive green dye showed that dye adsorption depends on the contact time, the dye concentration, and the pH equilibrium. Different concentrations of the prepared activated carbon were used with different dye concentrations and evaluated for dye removal efficiency. The maximum dye adsorption in this study was achieved after 270 min at a pH range of 5-9. In this study, the functional groups in the prepared ADS were identified using Fourier transform infrared (FTIR) while the crystal size was determined using an X-ray diffractometer (XRD). The Langmuir and Freundlich isotherm equation were used to study the adsorption kinetics, isotherms, and dye desorption while the pseudo-second-order kinetics was used to analyze the equilibrium adsorption data of the reactive green dye on the prepared ADS. The dyes’ adsorption kinetics followed pseudo-second-order kinetics, which is adjudged as the best in adsorption studies. The equilibrium data were best fitted with the Freundlich isotherm model. Conclusively, the adsorption of dye onto the prepared ADS was observed to be an endothermic physical adsorption process.

Keywords

[1] R.V. Kandisa, N.S. KV, K.B. Saik and RG.
GITAM, “Dye Removal by Adsorption,” Journal of
Bioremediation & Biodegradation, Vol.7, No.21, pp. 1-
4, 2016.
[2] K. R.T. Viraraghavan, “Dye Removal Using LowCost Adsorbents,” Water Science and Technology, Vol.
36, No.2-3, pp. 189-196, 1997.
[3] K. A. Adegoke, O.S. Bello, “Dye sequestration
using agricultural wastes as adsorbents,” Water Science
and Technology, Vol.12, No.8-24, pp.8-24, 2015.
[4] N.M, Mahmoodi, B. Hayati, M. Arami, “Textile
Dye Removal from Single and Ternary Systems Using
Date Stones: Kinetic, Isotherm, and Thermodynamic
Studies,” Zhejian Position Technology, Vol. 55 No.11,
p.p 4638–4649, 2010.
[5] N. Mathur, P. Bhatnagar, P. Bakre, “Assessing
mutagenicity of textile dyes from pali (Rajasthan) using
ames bioassay,” Applied Ecology and Environmental
Research, Vol. 4, No. 1, pp. 111–118, 2006.
[6] N. Mohan, N. Balasubramanian, C.A. Basha,
“Electrochemical oxidation of textile wastewater and its
reuse,” Journal of Hazardous Materials, Vol. 147, pp.
644–651, 2007.
[7] M.K. Sharma, R.C. Sobti, Rec, “Effect of certain
textile dyes in Bacillus subtilis,” Mutation Research
Elsevier, Vol. 465, pp. 27–38, 2000.
[8] E. Argun, S. Dursun, C. Ozdemir, M. Karatas,
“Heavy Metal Adsorption by Modified Oak Sawdust:
Thermodynamics and Kinetics,” Journal of Hazardous
Materials, Vol. 141, pp. 77–85, 2007.
[9] M.K. Aroua, S.P.P. Leong, L.Y. Teo, C.Y. Yin,
W.M.A.W. Daud, “Real-time Determination of
Kinetics of Adsorption of Lead (II) onto Palm ShellBased,” NCBI, Vol. 12, pp. 8–24, 2015.
[10] L.M.K. Elamrani, O. Cherkaoui, “Removal of
Two Cationic Dyes from a Textile Effluent by filtrationAdsorption on Wood Sawdust,” NCBI, Vol. 14, No.4,
pp. 240-237, 2007.
[11] A. Essawy, El-Hag Ali, M.S.A. Abdel-Mottaleb,
“Application of Novel Copolymer-Tio2 Membranes for
Some Textile Dyes Adsorptive Removal From Aqueous
Solution and Photocatalytic Decolorization,” Journal of
Hazardous Materials,Vol. 157, pp. 547–552, 2008.
[12] B.H. Hameed, H. Hakimi, “Utilization of durian
(Durio zibethinus Murray) Peel as Low-Cost Sorbent
for the Removal of Acid Dye from Aqueous Solutions,”
Journal of Biochemical Engineering, Vol. 39, No.2, pp.
338– 343, 2008.
[13] R. Liu, B. Zhang, D. Mei, H Zhang, J. Liu,
“Adsorption of Methyl Violet from Aqueous Solution
by Halloy Site Nanotubes,” Desalination, Elsivier.com,
Vol. 268, No.1–3, pp. 111–116, 2011.
[14] K. Steve, T. Erika, T. Reynold, and M. Paul,
“Activated Carbon: A Unit Operations and Processes of
Activated Carbon,” Open Access Library Journal, Vol.
25, pp. 350–749, 1998.
[15] N.J.N. Losso, W.E. Marshall, and R.M. Rao,
“Freundlich adsorption isotherms of agricultural byproduct-based powdered activated carbons in a geosm
in water system,” Journal of Thermodynamics, Vol. 85,
No. 2, pp. 131–135, 2002.
[16] F. Halbus, Z.H. Athab F.H. Hussein “Adsorption
of Disperse Blue Dye on Iraqi Date Palm Seeds
Activated Carbon,” Int. J. Chem. Sci, Vol.11, No.3, pp.
1219-1233, 2013.
[17] G. Blanchard, M. Maunaye and G. Martin,
“Removal of Heavy Metals from Waters by Means of
Natural Zeolites,” Water Research, Vol.18, No.12, pp.
1501-1507, 1984.
[18] R. Katal, M.S. Baei, H.T. Rahmati and H.
Esfandian, “Kinetic Isotherm and Thermodynamic
Study of Nitrate Adsorption From Aqueous Solutions
Using Modified Rice Husk,” Journal of Industrial and
Engineering Chemistry, Vol. 18, No. 1, pp. 295-302,
2012.
[19] O.W. Fritz, J. Huttinger, “Active sites and intrinsic
rates of carbon-gas reactions—a definite confirmation
with the carbon-carbon dioxide reaction,” Carbon
Elsevier, Vol. 31, pp. 923-930, 1993.
[20] A. Hema, S. Arivoli, “Comparative study on the
adsorption kinetics and thermodynamics of dyes onto
acid activated low-cost carbon, International Journal of
Physical Sciences, Vol. 2, pp.10–17, 2007.