Document Type : Research Paper

Authors

1 Materials Engineering Department, University of Technology, Baghdad.

2 Environmental Research Center, University of Technology - Iraq

Abstract

Thirty-five soil samples were collected from the Tanning Factory Industrial District within Baghdad city to investigate the soil pollution occur through four directions of the tanning plant. The soil samples exhibited high concentrations of Cr than the reported values of worldwide mean of unpolluted soils. The geoaccumulation index showed that the soil samples were moderately polluted by Cr at the north of the factory while the soil sample showed extremely polluted at the south and east of the factory. Moreover, the soil samples collected from west of the factory were strongly polluted. The result of the calculated enrichment factor (64.52-1075.22) showed to extremely high enriched and suggesting a significant role of anthropogenic pollution because of various industrial activities by the Tanning Factory.

Keywords

Main Subjects

[1] A.H.M.H. Al Obaidy, and A.A.M. Al Mashhadi, “Heavy Metal Contaminations in Urban Soil within Baghdad City, Iraq, Journal of Environmental Protection, 4, 1, 72-82, 2013.
[2] T.B. Chen, Y.M. Zheng, M. Lei, Z.C. Huang, H.T. Wu, H. Chen, K.K. Fan, K. Yu, X. Wu and Q.Z. Tian, “Assessment of Heavy Metal Pollution in Surface Soils of Urban Parks in Beijing, China,” Chemosphere, 60, 4, 542-551, 2005.
[3] C.M. Aelion, H.T. Davis, S. McDermott, A.B. Lawson and A.B. Lawson, “Metal Concentrations in Rural Topsoil in South Carolina: Potential for Human Health Impact, Science of the Total Environment, 402, 2-3, 149-56, 2008.
[4] A.S. Knox, A.P. Gamerdinger, D.C. Adriano, R.K. Kokla and D.I. Kaplan, “Sources and Practices Contributing to Soil Contamination,” In: Bioremediation of Contaiminated Soils, Adriano, D.C. Bollag, J.M., Frankenberger, Jr., W.T. and Sims, R.C. Eds. No. 37, Ch. 4, 1999.
[5] E. De Miguel, M. Jiménez de Grado, J.F. Llamas, A. Mart.n-Dorado and L.F. Mazadiego, “The Overlooked Contribution of Compost Application to the Trace Elements in Playgrounds in Madrid, Spain,” Science of the Total Environment, 215, 1-2, 113-122, 1998.
[6] L. Madrid, E. D.az-Barrientos and F. Madrid, “Distribution of Heavy Metal Contents of Urban Soils in Parks of Seville, Chemosphere, 49, 10, 1301 1308, 2002.
[7] A.A. Belay, “Impacts of Chromium from Tannery Effluent and Evaluation of Alternative Treatment Options,” Journal of Environmental Protection. 1, 53, 2010.
[8] O.E. Timothey, In Situ Treatment of soil and Groundwater Contaminated with Chromium, Technical Resource Guide, 2000.
[9] Z. Krejpcio, “Essentiality of Chromium for Human Nutrition and Health,” Pol. J. Environ. Stud., 10, 6, 399, 2001.
[10] R. Eisler, “Chromium Hazards to Fish, Wildlife and Invertebrates: A Synoptic Review. Laurel, MD 20708. 1986.
[11] Occupational Safety and Health Administration. Small Entity Compliance Guide for the Hexavalent Chromium Standards. 2006.
[12] J. Wyszkowska, “Soil Contamination by Chromium and Its Enzymatic Activity and Yielding,” Pol. J. Environ. Stud., 11, 1, 79, 2002.
[13] A.S. Al-Adili, “Geotechnical Evaluation of Baghdad Soil Subsidence and Their Treatments,” Thesis, University of Baghdad, 1998.
[14] A.L. Page, R.H. Miller and D.R. Keeney, “Methods of Soil Analysis,” Part 2, 2nd Edition, Agron. Monogr, ASA and SSSA, Madison, 1982.
[15] A. Kabata-Pendias and H. Pendias, “Trace Element in Soils and Plants,” CRC Press, London, 2001.
[16] B.J. Alloway, “Heavy Metals in Soils,” Blackie Academic and Professional, London, 1995.
[17] J.P. Riley and R. Chester, “Introduction to Marine Chemistry,” Academic Press, London, 1971.
[18] G. Müller, “Index of Geoaccumulation in Sediments of the Rhine River,” Geojournal 2, 3, 108-118, 1969.
[19] K.K. Loska, J. Cebula, J. Pelczar, D. Wiechula and J. Kwapulinski, “Use of Enrichment and Contamination Factors Together with Geoaccumulation Indexes to Evaluate the Content of Cd, Cu and Ni in the Rybnik Water Reservoir in Poland,” Water, Air, and Soil Pollution, 93, 1, 347-365, 1997.
[20] G.M.S. Abrahim and R.J. Parker, “Assessment of Heavy Metal Enrichment Factors and the Degree of Contamination in Marine Sediments fromTamaki Estuary, Aukland, New Zealand,” Environmental Monitoring and Assessment, 136, 1-3, 227-238, 2008.
[21] P. Quevauviller, R. Lavigne and L. Cortez, “Impact of Industrial and Mine Drainage Wastes on the Heavy Metal Distribution in the Drainage Basin and Estuary of the Sado River, Portugal,” Environmental Pollution, 59, 4, 267-286, 1989.
[22] K.C. Schiff and S.B. Weisberg, “Iron as a Reference Element for Determining Trace Metal Enrichment in Southern California Coastal Shelf Sediments,” Marian Environmental Research 48, 2, 161-176, 1999.
[23] C. Reimann and P. de Caritat, “Intrinsic Flaws of Element Enrichment Factors in Environmental Geochemistry,” Environmental Science and Technology, 34, 24, 5084-5091, 2000.
[24] V.K. Tippie, “An Environmental Characterization of Chesapeake Bay and a Frame Work for Action,” In: V. Kennedy, Ed., The Estuary as a Filter, Academic Press, New York, 1984.
[25] R. Rubio and F. Vilas, “Geochemistry of Major and Trace Elements in Sediments of the Ria de Vigo (NW Spain) an Assessment of Metal Pollution,” Marine Pollution Bulletin, 40, 11, 968-980, 2000.
[26] R.A. Sutherland, Bed Sediment Associated Trace Metals in an Urban Stream, Oahu, Hawaii,” Environmental Geology, 39, 6, 611-627, 2000.