Authors

1 Laser and Optoelectronic Engineering Dept., University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.

2 Laser and Optoelectronics Engineering Department- University of Technology-Iraq-Baghdad

Abstract

In this paper, the effect of using laser ablation of pure gold targets to obtain gold Nano rods and for pure zinc targets to obtain zinc oxide nanoparticles was studied separately in ethanol using an Nd:YAG laser tattoo removal (nanosecond pulses) and then mixing the resulting mixtures to obtain gold dopant with zinc oxide. Transmission electron microscopy (TEM), (XRD) X-Ray Diffraction and the optical properties were used to characterize the pure gold Nano rods, ZnO nanoparticles, and Au doped ZnO nanoparticles. Based on XRD and TEM, the results revealed the properties of the produced gold Nano roads. The obtained results indicated that the gold Nano rods produced by the 1064nm laser have superior optical, structural, and morphological properties and can be used in different sensors.

Graphical Abstract

Highlights

  • Using laser ablation of pure gold targets to obtain gold Nano rods.
  • A cheap pulsed laser source was used to prepare gold Nano rods.
  • Zinc-doped gold Nano rods were prepared to fabricate optical and biological sensors.

          The fabricated Zinc-doped gold Nano rods shave superior optical, structural, and morphological properties and  can be    in different sensors.

Keywords

Main Subjects

[1] E. Solati, and D. Dorranian, Comparison between silver and gold nanoparticles prepared by pulsed laser ablation in distilled water,  Journal of Cluster Science, 26 (2015) 727-742, DOI: 10.1007/s10876-014-0732-2
[2] H. S. Ali, M. A. Fakhri, and Z. Khalifa. Optical and structural properties of the gold nanoparticles ablated by laser ablation in ethanol for biosensors , J. Phys.: Conf. Ser.  1795 (2021) 012065.
[3] D. Riabinina, J. Zhang, M. Chaker, and D. Ma, Size control of gold nanoparticles synthesized by laser ablation in liquid Media, ISRN Nanotechnology, 2012 (2012) 1-5,
doi.org/10.5402/2012/297863
[4] K. I. Hassoon, S. H. Sabeeh, and M. A. Khalaf, ZnO nano particles (NPs) properties prepared by liquid phase laser ablation (LPLA), Al-Nahrain Journal of Science,  20 (2017) 70-77.
[5] V. Amendola, S. Polizzi, and M. Meneghetti, Laser ablation synthesis of gold nanoparticles in organic solvents, Phys. Chem. B, 110 (2006) 7232-7237.
[6] Z.Yan, D. B.Chrisey, Pulsed laser ablation in liquid for micro-/nanostructure generation, Journal of Photochemistry and Photobiology C: Photochemistry Reviews,  13 (2012) 204-223.
[7] F. Correard, K. Maximova, M. EstèveC. VillardM. RoyA. Al-Kattan, M. SentisM. GingrasA. V Kabashin, and D. Braguer, Gold nanoparticles prepared by laser ablation in aqueous biocompatible solutions : assessment of safety and biological identity for Nano medicine applications, Int J Nanomedicine, 9 (2014) 5415–5430.
[8] S. A. Adnan, Z. H. Tawfiq, and M. A. Fakhri, Gold nanoparticles in liquid based on photonic crystal fiber PCF for sensors application, Defect and Diffusion Forum, 398 (2020) 23-28.
[9] S. M.Faydh, A. K. Al-Ogaili, and E. T. Salim, Effect of the laser shock processing on wear resistance of brass alloy, Eng. &Tech. Journal, 32 (2014) 998-1008.
[10] Z. H. Tawfiq, S. A. Adnan, M. A. Fakhri, and R. K. Hamad, Structural, morphological and optical properties of gold nanoparticles using laser ablation in liquid for sensor applications, Iraqi Journal of Computers, Communication, Comtrol & Systems Engineering, 19 (2019) 30-35.
[11] M. Das, K. H. Shim, S. S. A. An, and D. K.Yi, Review on gold nanoparticles and their applications, JTEHS, 3 (2011) 193–205.
[12] D. Zhang, B. Gökce, and S. Barcikowski, Laser synthesis and processing of colloids: fundamentals and applications, Chem. Rev.,  117 (2017) 3990–4103.
[13] N. Mirghassemzadeh, M. Ghamkhari, and D. Dorranian, Dependence of laser ablation produced gold nanoparticles characteristics on the fluence of laser pulse, Soft Nano science Letters, 2013 (2013) 101-106.
[14] M.A. Fakhri, E. T. Salim, M.H.A. Wahid, A. W. Abdulwahhab, Z. T. Salim, and U. Hashim, Heat treatment assistedspin coating for LiNbO3 films preparation: their physical properties, J Phys Chem Solids, 131 (2019) 180-188.
[15] J. Sylvestre, S. Poulin, Andrei V. Kabashin, E. Sacher, M. Meunier, and J. H. T. Luong, Surface chemistry of gold nanoparticles produced by laser ablation in aqueous media, J. Phys. Chem. B, 108 (2004) 16864-16869.
[16] E. T. Salim, J. A. Saimon, M. K Abood, and M. A Fakhri. Effect of ammonium concentration on structural, optical and morphological properties of H-Nb2O5 thin films—A novel study, Materials Research Express, 6 (2019) 046420.
[17] D. Riabinina and M. Chaker, Dependence of gold nanoparticle production on pulse duration by laser ablation in liquid media, Nanotechnology, 23 (2012) 135603.
[18] V. Lehmann and U. Gösele, Porous silicon formation : A quantum wire effect, Appl. Phys. Let., 58 (1991) 856-858.
[19] B. M. P. Stewart and J. M. Buriak, Chemical and biological applications of porous silicon technology, Adv. Mater, 12 (2000) 859-869.
[20] Z. H Tawfiq, M. A Fakhri, and S. A. Adnan, Photonic crystal fibres PCF for different sensors in review, IOP Conference Series: Materials Science and Engineering, 454 (2018) 012173.
[21] C. Wang, X. Wang, B. Q. Xua, J. Zhao, B. Mai, P. Peng, G. Sheng, and J. Fu, Enhanced photocatalytic performance of nanosized coupled ZnO/SnO2 photocatalysts for methyl orange degradation, J. Photochem. Photobiol A., 168 (2004) 47-52.
[22] C. Cheng, A. Amini, C. Zhu, Z. Xu, H. Song, and N. Wang, Enhanced photocatalytic performance of TiO2-ZnO hybrid nanostructures, Sci. Rep. 4 (2014) 4181-4185.
[23]  M. Misra, P. Kapur, and M. L. Singla, Surface plasmon quenched of near band edge emission and enhanced visible photocatalytic activity of Au@ZnO core-shell nanostructure, Appl. Catal. B: Environ. 150-151 (2014) 605-611.
[24] Y., Xu, B., Yao, Y. F., Li, Z. H., Ding, J. C., Li, H. Z., Wang, and D. Z. Shen, Chemical states of gold doped in ZnO films and its effect on electrical and optical properties, J. Alloys Compd, 585 (2014) 479–484.
[25] H., Xie, F., Ding, & H. Mu, Effects of Au nanoparticles and ZnO morphology on the photocatalytic performance of Au doped ZnO/TiO2 films, Nanotechnology,  30 (2018) 085708.
[26] M. A Fakhry, F. A. Hattab, and E. K. Hamed, Laser energy effects on optical properties of titanium di-oxide prepared by reactive pulsed laser deposition, Eng. Technol. J., 30 (2012) 3104-3111.
[27] C. Byram, and V. R. Soma, 2, 4-Dinitrotoluene detected using portable raman spectrometer and femtosecond laser fabricated Au–Ag nanoparticles and nanostructures, Nano-Structures & Nano-Objects, 12 (2017) 121–129.
[28] M. Khenfouch O. Bajjou, M. Baïtoul, N. Mongwaketsi, M. Maaza, and J. W. Venturini, Optical properties and dynamics excitation relaxation in reduced graphene oxide functionalized with nanostructured porphyries, Optical Materials, 42 (2015) 479–483.
[29] E. T. Salem & F. A. Mohamed, Preparation and characterization of MOS device using MgO Film as a dielectric material, Eng. Technol. J., 28 (2010) 6253-6262.
[30] G K Prashanth, P. A. Prashanth , P. Singh , B. M. Nagabhushana , C. Shivakumara , G M Krishnaiah, H. G. Nagendra , H. M. Sathyananda & V. Chaturvedi, Effect of doping (with cobalt or nickel) and UV exposure on the antibacterial, anticancer, and ROS generation activities of zinc oxide nanoparticles, J. Asian Ceram. Soc., 8 (2020) 1175-1187. 
[31] V. PerumalU. HashimS. C. B. GopinathH. R. PrasadL. Wei-WenS. R. BalakrishnanT. Vijayakumar, and R. A. Rahim, Characterization of gold-sputtered zinc oxide nanorods—a potential hybrid material, Nanoscale Res Lett., 11 (2016) 1-11.
[32] M. A. Fakhri, Effect of substrate temperature on optical and structural properties of indium oxide thin films prepared by reactive PLD method, Eng. Technol. J., 32 (2014) 1323-1330.
[33] C. Wang and T. Wang, Synthesis and optical properties of colloidal gold nanoparticles synthesis and optical properties of colloidal gold nanoparticles, J. Phys. Conf. Ser, 187 (2009) 012026.
[34] S. B. Kolavekara, N.H. Ayachitb, G. Jagannathc, K. N.Krishnakanthd, and S. V. Rao, Optical, structural and Near-IR NLO properties of gold nanoparticles doped sodium zinc borate glasses, Optical Materials, 83 (2018) 34–42.
[35] E. T. Salim, and H. H. Rashed, Laser pulses effect on the structural and optical properties of ZnO Nano particles prepared by laser ablation in water, Eng. Technol. J., 32 (2014) 198-207.