Document Type : Research Paper

Authors

1 materials engineering, university of technology, Baghdad, Iraq

2 material engineering, university of technology

3 Materials engineering, university of technology

Abstract

Recently, geopolymers have received widespread attention due to their ability to completely replace ordinary cement with better efficiency, lower cost, and less damage to the climatic environment. This paper aimed to prepare MK-based geopolymer cement at ambient temperature with different alkaline activators and processing parameters. XRD, PSA, DTA-TGA, SEM, and other techniques have characterized the prepared samples. ANOVA test was employed to identify the main effect of the processing parameters. Results showed that the incorporation of potassium ions has a negative effect on the physical properties of GP, in which the presence of such ions tends to decrease the density of GP. Furthermore, the apparent porosity and water absorption were increased. For Na and K, Na-activated GP, it was also concluded that the density of GP increases by increasing Si/Al ratios. Despite the Na-based GP processes having a larger density in compared to the K, Na-based ones. The results also suggested a strong effect of the W\MK ratio on physical properties, in which decreasing this ratio is necessary to achieve GP with better properties. The findings also revealed that a one-minute mixing period was sufficient for producing a homogeneous and dense GP paste.

Graphical Abstract

Highlights

  • The presence of K+ ions negatively influences GP's physical properties.
  • W/MK ratio is the most important factor that affects GP's physical properties.
  • Increasing the Si/Al ratio will lead to an increase in the density of GP.
  • Short mixing time is necessary to achieve better GP properties.

Keywords

Main Subjects

[1] Rangan, B Vijaya. Geopolymer Concrete for Environmental Protection. The Indian concrete journal,88  (2014) 41-59.
[2] Provis, John L, and Jan Stephanus Jakob Van Deventer. Geopolymers: Structures, Processing, Properties and Industrial Applications. Elsevier, 2009.
[3] Luukkonen, Tero, Zahra Abdollahnejad, Juho Yliniemi, Paivo Kinnunen, and Mirja Illikainen. One-Part Alkali-Activated Materials: A Review. Cement and Concrete Research. 103 (2018) 21-34. doi.org/10.1016/j.cemconres.2017.10.001
[4] Abdullah, MM, Liew Yun Ming, Heah Cheng Yong, and MF Tahir. "Clay-Based Materials in Geopolymer Technology." Cement Based Material. 1nd ed. London.: IntechOpen  2018. DOI: 10.5772/intechopen.74438.
[5] Khatib, Jamal. Sustainability of Construction Materials. Woodhead Publishing, 2016.
[6] Liew, Yun-Ming, Cheng-Yong Heah, and Hussin Kamarudin. Structure and properties of clay-based geopolymer cements: A review. Progress in Materials Science 83 (2016) 595-629.‏ doi.org/10.1016/j.pmatsci.2016.08.002.
[7] Rahier, H., et al., Reaction mechanism, kinetics and high temperature transformations of geopolymers. Journal of Materials Science, (2007) 2982- 2996. DOI: 10.1007/s10853-006-0568-8.
[8] Khale, Divya, and Rubina Chaudhary. Mechanism of geopolymerization and factors influencing its development: a review. Journal of materials science. 42.3 (2007) 729-746.‏ doi.org/10.1007/s10853-006-0401-4.
[9] Duxson, P. S. W. M., et al. The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects,292.1(2007)8-20.‏ doi.org/10.1016/j.colsurfa.2006.05.044.
[10] Aboulayt, A, M Riahi, M Ouazzani Touhami, H Hannache, M Gomina, and RJAPT Moussa. Properties of Metakaolin Based Geopolymer Incorporating Calcium Carbonate Advanced Powder Technology, 28 (2017) 2393-401. doi.org/10.1016/j.apt.2017.06.022.
[11] van Jaarsveld, JGSav, and JSJ Van Deventer. Effect of the Alkali Metal Activator on the Properties of Fly Ash-Based Geopolymers. Industrial & engineering chemistry research, 38 (1999) 3932-41. doi.org/10.1021/ie980804b.
[12] Lizcano, Maricela, Hyun Soo Kim, Sandip Basu, and Miladin Radovic. Mechanical Properties of Sodium and Potassium Activated Metakaolin-Based Geopolymers. Journal of Materials Science, 47 (2012) 2607-16. doi.org/10.1007/s10853-011-6085-4.
[13] ASTM standards: C373-88, standard test method for water absorption, bulk density, apparent porosity and apparent specific gravity of fired white ware products (1999).
[14] Alomayri, Thamer. Effect of Glass Microfibre Addition on the Mechanical Performances of Fly Ash-Based Geopolymer Composites. J. Asian Ceram. Soc. 5 (2017) 334-40. doi.org/10.1016/j.jascer.2017.06.007.
[15] Rashad, Alaa M. Metakaolin as Cementitious Material: History, Scours, Production and Composition–a Comprehensive Overview. Construction and building materials, 41 (2013) 303-18. doi.org/10.1016/j.conbuildmat.2012.12.001.
[16] Ptáček, Petr, Dana Kubátová, Jaromír Havlica, Jiří Brandštetr, František Šoukal, and Tomáš Opravil. Isothermal Kinetic Analysis of the Thermal Decomposition of Kaolinite: The Thermogravimetric Study. Thermochimica Acta, 501 (2010) 24-29. doi.org/10.1016/j.tca.2009.12.018.
[17]   Ptáček, Petr, František Šoukal, Tomáš Opravil, Jaromír Havlica, and Jiří Brandštetr. The Kinetic Analysis of  the Thermal Decomposition of Kaolinite by Dtg Technique. Powder Technology, 208 (2011)20-25. doi.org/10.1016/j.powtec.2010.11.035.
[18] Khan, M Irfan, Hafeez Ullah Khan, Khairun Azizli, Suriati Sufian, Zakaria Man, Ahmer Ali Siyal, Nawshad Muhammad, and M Faiz ur Rehman. The Pyrolysis Kinetics of the Conversion of Malaysian Kaolin to Metakaolin. Appl. Clay Sci. 146 (2017) 152-61. doi.org/10.1016/j.clay.2017.05.017.
[19] Murray, Haydn H. Applied Clay Mineralogy: Occurrences, Processing and Applications of Kaolins, Bentonites, Palygorskitesepiolite, and Common Clays. Elsevier, 2006. doi.org/10.1007/BF03406033.
[20]    Johnson, EBG, Sazmal E Arshad, and Jahimin Asik. Hydrothermal Synthesis of Zeolite a Using Natural Kaolin from Kg. Gading Bongawan Sabah. Can. J. Appl. Sci.               Canadian, 14 (2014) 3282-87. DOI: 10.3923/jas.2014.3282.3287.
[21] Andrades, Raphael Cons, Roberto Freitas Neves, Francisco Rolando Valenzuela Díaz, and Antonio Hortencio Munhoz Júnior. Influence of Alkalinity on the Synthesis of Zeolite a and Hydroxysodalite from Metakaolin. Paper presented at the J. Nano Res. 2020. doi.org/10.4028/www.scientific.net/JNanoR.61.51.
[22] Alshaaer, Mazen, B El-Eswed, RI Yousef, F Khalili, and H Rahier. Development of Functional Geopolymers for Water Purification, and  Construction Purposes, J. Saudi Chem. Soc. 20(2016)S85-S92. doi.org/10.1016/j.jscs.2012.09.012.
[23] Chindaprasirt, Prinya, Pre De Silva, and Sakonwan Hanjitsuwan. Effect of High-Speed Mixing on Properties of High Calcium Fly Ash Geopolymer Paste. Arabian Journal for Science and Engineering, 39 (2014) 6001-07. doi.org/10.1007/s13369-014-1217-1.
[24] Zhang, Zuhua, and Hao Wang. The Pore Characteristics of Geopolymer Foam Concrete and Their Impact on the Compressive Strength and Modulus. Front. Mater. 3 (2016) 38. DOI: 10.3389/fmats.2016.00038.
[25]   Farhana, ZF, H Kamarudin, Azmi Rahmat, and  AM Al Bakri. The  Relationship between Water Absorption and Porosity for Geopolymer Paste. Paper presented at the Materials Science Forum, 2015. DOI: 10.4028/www.scientific.net/MSF.803.166.
[26]   Jamil, NH, WMAW Ibrahim, MMAB Abdullah, AV Sandu, and MFM Tahir. Fabrication of Porous Ceramic-Geopolymer Based Material to Improve Water Absorption and Retention in Construction Materials: A Review. Paper presented at the IOP Conference Series: Materials Science and Engineering, 2017. DOI: 10.1088/1757-899X/209/1/012004.
[27] Azhar, Nor Shida Dalila Mohd, Farah Farhana Zainal, and Mohd Mustafa Al Bakri Abdullah. Effect of Different Ratio of Geopolymer Paste Based Fly Ash-Metakaolin on Compressive Strength and Water Absorption. Paper presented at the IOP Conference Series: Materials Science and Engineering, 2019. DOI: 10.1088/1757-899X/701/1/012010.
[28] Razak, SitiAisyah, Farah Farhana Zainal, and Shaiful Rizam Shamsudin. Effect of Porosity and Water Absorption on Compressive Strength of Fly Ash Based Geopolymer and Opc Paste. Paper presented at the IOP Conference Series: Materials Science and Engineering, 2020.  DOI: 10.1088/1757-899X/957/1/012035.
[29] Sindhunata, J. S. J. Van Deventer, G. C. Lukey, and H. Xu, Effect of curing temperature and silicate concentration on fly-ash-based geopolymerization, Ind. Eng. Chem. Res., 45 (2006) 3559–3568.doi.org/10.1021/ie051251p.
[30] M. Criado, A. Fernández-Jiménez, A. G. De La Torre, M. A. G. Aranda, and A. Palomo, An XRD study of the effect of the SiO2/Na2O ratio on the alkali activation of fly ash, Cem. Concr. Res., 37 (2007) 671–679.doi.org/10.1016/j.cemconres.2007.01.013.