Document Type : Research Paper

Authors

University of Technology-Iraq

Abstract

Recycling consumed commercial polymers is considered a highly important issue that chemists and engineers must take care of to develop the proper recycling techniques. The main objective of this study is to find a radical solution to the problems of plastic waste by recycling plastic waste (water bottles) and studying the effect of the produced Degraded Polyethylene Terephthalate (DPET) on the properties of paints. DEPT was added in six quantities to the paint mixture (1, 3, 4, 5, 7, and 14 grams). The paints were evaluated using various tests, including scanning electron microscopy (SEM), viscosity, adhesion, brightness, color, ultraviolet reflectance, and accelerated weathering. Testing the paint mixtures showed that the samples were not affected by weather conditions. This indicates the improvement of the paint mixtures by adding quantities of DPET. This study concludes that the catalyst ratios used succeeded in cracking DPET and avoided the need for large quantities of the catalyst. The use of  DPET in various material applications reduces the cost due to the low cost of DPET production. The use of PET in sustainable applications conferred a radical solution to plastic waste problems worldwide. In this work, mixing plastic waste products, after their treatment, in the preparation of paint mixtures successfully contributed to improving the required specifications.

Graphical Abstract

Highlights

  • Chemical recycling of plastic water bottles by Depolymerization process.
  • Improving the specifications of paints materials by polyethylene terephthalate

Keywords

Main Subjects

[1] Alzuhairi, M.A., Khalil, B.I., and Hadi, R.S., Nano  ZnO catalyst for chemical recycling of polyethylene terephthalate (PET). Eng. Technol.  J.,35 (2017) 831–837.
[2] Alzuhairi, M.A., Khalil, B.I., and Hadi, R.S. Nano  ZnO catalyst for chemical recycling of polyethylene terephthalate (PET). Eng. Technol.  J.,35 (2017) 831–837.
[3] Alzuhairi, M., 2018, Bubble column and CFD simulation for chemical recycling of poly- ethylene terephthalate. AIP Conference Proceedings ,1,2018,030041.
[4] Hussein, A.A., Alzuhairi,  M., and Aljanabi, N.H., Degradation and depolymerization of plastic waste by local bacterial  isolates and bubble column reactor. AIP Conference Proceedings 1 ,2018,030041.
[5] Zahraa A. Hussein, Zaidoon M. Shakor, Mohammed Alzuhairi & Farooq AlSheikh, 2021, Thermal and catalytic cracking of plastic waste: a review, Int. J. Environ. Anal. Chem.
[6] Halla Mohammeda, Mohammed Alzuhairi , Sarmad I. Ibrahima and Saif S. Hussien, 2021, Ternary waste plastic blends for binding and adhesion. Int. J. Environ. Stud.
[7] Saleh, T.A.; Danmaliki, G.I. Polymer Consumption, Environmental Concerns, Possible Disposal Options, and Recycling forWater Treatment. In Advanced Nanomaterials for Water Engineering, Treatment, and Hydraulics; IGI Global: Hershey, PA, USA, 2017.
[8] Favis, B.D.; Le Corroller, P. Polymeric material and process for recycling plastic blends. U.S. Patent 9,670,344, 6 July 2017.
[9] D. Lazarevic, E. Aoustin, N. Buclet, and N. Brandt, Plastic waste management in the context  of a European recycling society: Comparing results and uncertainties in a life cycle perspective, Resour. Conserv. Recycl., 55 (2010) 246–259.
[10] L. Bartolome, M. Imran, B. G. Cho, W. A. Al-Masry, and D. H. Kim, Recent developments in the chemical recycling of PET, Mater. Recycl. Perspect., 406 (2012).
[11] Sulyman, M., Haponiuk, J., & Formela, K.  International Journal of Environmental Science and Development, 7 (2016) 100.
[12] A. M. Al-Sabagh, F. Z. Yehia, G. Eshaq, A. M. Rabie, and A. E. ElMetwally, Greener routes for recycling of polyethylene terephthalate, Egypt. J. Pet., 25 (2016) 53–64.
[13] Tiseo, I. Global PET Bottle Production 2004–2021. Available online :( accessed on 28 March 2021) (2021).
[14] Mohammed, Azad A. Flexural behaviour and analysis of reinforced concrete beams made of recycled PET waste concrete. Constr. Build. Mater. 155 (2017): 593-604.‏
[15] Webb, Hayden K., et al. Plastic degradation and its environmental implications with special reference to poly (ethylene terephthalate). Polymers 5.1 (2013) 1-18.
[16] Da Silva, Lucas Filipe Martins, Andreas Öchsner, and Robert D. Adams, eds. Handbook of adhesion technology,Heidelberg: Springer.‏2011.
[17] Li, Hui, et al. Microstructure of cement mortar with nano-particles. Composites part B: engineering .35.2 (2004) 185-189.‏