Document Type : Research Paper

Authors

Civil Engineering Dept., University of Technology-Iraq, Alsina’a Street, 10066 Baghdad, Iraq.

Abstract

Global warming on planet Earth results from the high emission of greenhouse gases, especially CO2. The Portland cement industry releases high amounts of CO2 and is responsible for about 5-8% of total emissions. Efforts have been made to look for alternative cementless binders to mitigate the impact on the environment. Geopolymers are one of the highlighted alternatives and can be obtained from the reaction of any aluminosilicate material with an alkaline solution. Aluminosilicate materials are found in byproduct materials such as fly ash. Geopolymer concrete is a promising environmentally friendly option. However, previous conventional mix proportioning methods for fly ash-based Geopolymer concrete have been limited. Most of these methods focused on a single weight ratio of SiO2/Na2O, which was 2. However, the sodium silicate solution is produced industrially with various concentrations depending on the weight ratio of SiO2/Na2O. Adding sodium hydroxide to the sodium silicate solution increases the alkalinity of the resulting activation liquid. This work proposes a new mix proportioning procedure named the "Ratio of the Resulting Sodium Silicate Method for Geopolymer Binder." The method has been successfully verified to achieve the desired compressive strength on the 7th and 28th days. We also tested different control specimens from previous studies using this new proposal to study the effect of different parameters on compressive strength predictions.

Graphical Abstract

Highlights

  • A new mix proportion design for fly ash geopolymer concrete is proposed.
  • The method allows the use of any sodium silicate solution, with the addition of flakes or pellets of sodium hydroxide.
  • There is no need to prepare sodium hydroxide at a specific molarity; it simplifies the process.
  • Compressive strength can be predicted accurately using the proposed Equation

Keywords

Main Subjects

  1. Portland Cement Association, Market Intelligence, World Cement Consumption, PCA, 2022. cement.org.
  2. Davidovits, High-Alkali Cements for 21st Century Concretes, in Concrete Technology, Past, Present and Future, Proceedings of V. Mohan Malhotra Symposium,144,1994,383-397. https://doi.org/10.14359/4523
  3. McCaffrey, R.. 2002 Climate Change and the Cement Industry, Global Cement and Lime Magazine (Environmental Special Issue), pp.15-19.
  4. Duxson, J.L. Provis, G.C. Lukey, The Role of Inorganic Polymer Technology in Developing Green Concrete, Cem. Concr. Res., 37 (2007) 1590-1597. http://dx.doi.org/10.1016/j.cemconres.2007.08.018
  5. Hardjito, D. and Rangan, B. V. Development and Properties of Low-Calcium Fly Ash-based Geopolymer Concrete, Research Report GC1, Faculty of Engineering, Curtin University of Technology, Perth, 2005.http://www.Geopolymer.org
  6. Black, J.R. Mix Design Process for Alkaline-Activated Class F Fly Ash Geopolymer Concrete, University of New South Wales at the Australian Defense Force Academy, LT, School of Engineering & Information Technology. ZEIT4500/4501, Final Project Report, 2012.
  7. O. Kayali, A. Khennane, A Detailed Procedure of Mix Design for Fly Ash Based Geopolymer Concrete, Fourth Asia-Pacific Conference on FRP in Structures (APFIS )11-13 December, Melbourne, Australia, International Institute for FRP in Construction, 2013.
  8. Davidovits, 2011. Geopolymer chemistry and applications 3rd edition, Geopolymer institute F-02100 Saint-Quentin, France, Vol. 612, pp. 289-291,433-435.http://www.Geopolymer.org
  9. Alhifadhi, M.A., al-Attar, T.S. and Hasan, Q.A. Structural Behavior of Reinforced Fly Ash Based Geopolymer Concrete T-beams, MSc research, Civil engineering department, University of Technology-Iraq, Iraq, 2015.
  10. Silverstrim, H. Rostami, J. C. Larralde and A. Samadi-Maybodi, Fly ash cementitious material and method making a product, US Patent 5,601,643,1997.
  11. Davidovits, J. Personal Communication on the Process of Making of Geopolymer Concrete, 2015.
  12. Rangan, Proceedings of the International Workshop on Geopolymer Cement and Concrete, Allied Publishers Private Limited, Mumbai, India, 2010, 68-106.
  13. F. Ahmed, M.F. Nuruddin, N. Shafiq‏, Compressive Strength and Workability Characteristics of Low-Calcium Fly ash-based Self-Compacting Geopolymer Concrete, Int. Sch. Sci. Res. Innov.,5 (2011) 64-7.