Author
Abstract
Three experiments were curried out at different reaction temperatures [ 250, 300,
330 oC ], for the reaction of silicon with methyl chloride in a fluidized bed reactor, in
order to evaluate a new predicted model that calculate both conversions of reacted solid
(silicon) and reacted gas (methyl chloride) as function of pressure drop along the bed.
The reacted gas velocity was selected to be above the minimum fluidization
velocity [velocity selected 2.6 cm/s, minimum fluidization velocity 1.8 cm/s] for the solid
particles (size used 130 μm). A digital pressure drop measuring device was used at three
points of the reactor (before and after the distributor and finally 50 cm above the
distributor), to determine the pressure drop along the column, also an online GC was
connected to the outlet reacted gas to analyze the product.
A comparison between the conversions of methyl chloride and silicon calculated
from pressure drop data and that detected by the online GC, show a proper agreement
with less than 5 %absolute average error.
Two equations [16, 18], derived analytically, were equation [8, 18] used to
calculate the conversion of silicon and methyl chloride as function of pressure drop,
equation [16] used to calculate the conversion of silicon as function of conversion of
methyl chloride.
Keywords
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