Effect of Halogen Ions on The Corrosion of Brass In Na2SO4 Solution
Engineering and Technology Journal,
2010, Volume 28, Issue 7, Pages 1386-1395
AbstractThis research involves study effect of halogen ions presence in 0.2M sodium
sulphate on the corrosion of brass at room temperature (30oC). Three concentration of
halogen ions (Fˉ, Clˉ, Brˉ, and Iˉ) were used 0.1, 0.2, and 0.3 M. The different in
corrosion parameters before and after added the halogen ions interpreted and
discussed which involves corrosion potentials (Ecorr), corrosion current densities
(icorr), and Tafel slops (bc & ba) in addition to discuss the polarization curves.
Polarization resistances (Rp) and the change in free energy (ΔG) were
calculated and interpreted, in addition to calculate the rate of corrosion (Rmpy).
The results of this work indicates that the presence of halogen ions in
experimental solution increases the rate of corrosion, and the effect of halogen ions
follows the sequence to increase the corrosion Iˉ > Clˉ > Fˉ > Brˉ.
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