Oxides of nitrogen (NO + NO2 , (NOx)) are emitted from refineries, not only contribute to the production of photochemical smog at ground level but also cause damage to plant life and add to the problem of acid rain. The small amounts of prompt NO produced in the furnace chambers and oil refineries because the formation of NOx can be attributed to four distinct chemical kinetic processes: thermal NOx formation, prompt NOx formation, fuel NOx formation, and intermediate N2O.
In this paper, the portions of pollutants that resulted in fuel burning (liquid or gas) in oil and gas refinery were studied by modeling of emitted gases in furnace chamber. The case study at Nassiriya power plant with different loads (70 – 210) MW was studied. The method of finite volume was studied to predict the pollutant portions by using FLUENT computer code (FLUENT is one of largest codes of computer programs which solve thousands of flow and combustion cases. The case study was drawn graphically then imported to solve by FLUENT). These types of pollution species are NOx and SOx as the important air pollutant influenced the human health. The numerical analysis in calculating the pollutants of chamber gave the findings of crude oil emission in combustion is higher than that at using gaseous fuel.
So, the methods of decreasing NOx and SOx pollution by water injection and exhaust gas recirculation are used in refinery operation were presented