A new wear resistance glass-ceramic coating system iron (low alloyed low carbon steel) based substrate was developed. The effects of heat treatment conditions and mill additions on wear resistance of developed coatings resistance were studied. The coating materials showed excellent properties for protection the iron substrate from wear. Also, in this work mathematical modeling is implemented and regression equations are obtained by using ( SPSS ) software to predict the experimental data for wear rate. Comparing the predicted and measured values gives high prediction accuracy.